Electroplating wastewater treatment by in-situ formation of organic anions and inorganic anions intercalated layered double hydroxides

The electroplating wastewater containing various metal ions was treated by adding sodium dodecyl benzene sulfonate (SDBS) and regulating pH value, and the resulting precipitates were characterized by X-ray diffraction (XRD). The results showed that organic anions intercalated layered double hydroxid...

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Bibliographic Details
Published in:Chemosphere (Oxford) 2023-10, Vol.338, p.139425-139425, Article 139425
Main Authors: Ruan, Xiuxiu, Zhu, Wangkai, Jiang, Zili, Zuo, Jianwei, Frost, Ray L., Ayoko, Godwin A., Qian, Guangren
Format: Article
Language:English
Subjects:
Competition mechanism
Layered double hydroxides
Ni–Fe ILDHs
Ni–Fe OLDHs
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Summary:The electroplating wastewater containing various metal ions was treated by adding sodium dodecyl benzene sulfonate (SDBS) and regulating pH value, and the resulting precipitates were characterized by X-ray diffraction (XRD). The results showed that organic anions intercalated layered double hydroxides (OLDHs) and inorganic anions intercalated layered double hydroxides (ILDHs) were in-situ formed to remove heavy metals during the treatment process. In order to reveal the formation mechanism of the precipitates, SDB− intercalated Ni–Fe OLDHs, NO3− intercalated Ni–Fe ILDHs and Fe3+-DBS complexes were synthsized by co-precipitation at various pH values for comparison. These samples were characterized by XRD, Fourier Transform infrared (FTIR), element analysis as well as the aqueous residual concentrations of Ni2+ and Fe3+ were detected. The results showed that OLDHs with good crystal structures can be formed as pH≤7, while ILDHs began to form at pH = 8. When pH 
ISSN:0045-6535
1879-1298
DOI:10.1016/j.chemosphere.2023.139425