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Sustainable biopolyol production via solvothermal liquefaction silvergrass saccharification residue: Experimental, economic, and environmental approach

With the rising environmental concern, sustainable chemistry should be accomplished by considering technical, economic, and environmental factors that guarantee the successful implementation of new alternative products. Hence, we performed the integrated techno-economic and life cycle assessment for...

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Published in:The Science of the total environment 2022-11, Vol.847, p.157668-157668, Article 157668
Main Authors: Tran, My Ha, Lee, Boreum, Lee, Hyunjun, Brigljević, Boris, Lee, Eun Yeol, Lim, Hankwon
Format: Article
Language:English
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Summary:With the rising environmental concern, sustainable chemistry should be accomplished by considering technical, economic, and environmental factors that guarantee the successful implementation of new alternative products. Hence, we performed the integrated techno-economic and life cycle assessment for two-step solvothermal liquefaction (two-pot synthesis) and simplified solvothermal liquefaction (one-pot synthesis) based on experiment results. Based on the itemized cost estimation, the unit biopolyol production costs obtained from the two-pot synthesis and one-pot synthesis were 10.0 $ kg−1 and 2.89 $ kg−1, respectively. To provide techno-economic guidelines for biopolyol production, profitability analysis, and uncertainty analysis were used to identify the economic feasibility of the proposed processes. In addition, the life cycle assessment results indicated that biopolyol production via the two-pot synthesis leads to a slightly lower greenhouse gas emission compared with the one-pot synthesis, which further required the use of an analytic hierarchy process to determine the best process for biopolyol production depending on the different weight points in the economic and environmental aspects. From these results, we can provide the technical performance, economic feasibility, and environmental impact of lab-scale biopolyol production from silvergrass residue, a low-cost waste of biomass saccharification. [Display omitted] •Biopolyol was produced from biomass as a valuable precursor for polymer synthesis.•Two concepts of lignin residue liquefaction were evaluated for biopolyol production.•Techno-economic assessment was performed using diverse economic analysis methods.•Biopolyol selling price is comparable compared to commercial petro-based polyol.•Several environmental impacts of biopolyol production were comprehensively studied.
ISSN:0048-9697
1879-1026
DOI:10.1016/j.scitotenv.2022.157668