Recent advances in structures and applications of coordination polymers based on cyclohexanepolycarboxylate ligands

Coordination polymers (CPs) are emerging crystalline materials constructed from metal entities and organic ligands through coordination bonds, containing infinite coordination units in one, two, or three dimensions. Here an overview is given of recent structural research based on seven cyclohexanepo...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2022-02, Vol.51 (8), p.2992-3003
Main Authors: Ou, Yong-Cong, Zhong, Ri-Ming, Wu, Jian-Zhong
Format: Article
Language:English
Subjects:
Coordination polymers
Ligands
Topology
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Summary:Coordination polymers (CPs) are emerging crystalline materials constructed from metal entities and organic ligands through coordination bonds, containing infinite coordination units in one, two, or three dimensions. Here an overview is given of recent structural research based on seven cyclohexanepolycarboxylates (CHPCs), namely cyclohexanecarboxylate, 1, -cyclohexanedicarboxylate ( = 2, 3, or 4), 1,3,5-cyclohexanetricarboxylate, 1,2,4,5-cyclohexanetetracarboxylate and 1,2,3,4,5,6-cyclohexanehexacarboxylate, showing the effects of the conformation transformation and auxiliary ligands on the dimensionality and the geometric topology of the assemblies generated. The applications of these CPs as platforms for molecular adsorption, luminescent sensing, magnetism, and catalysis are also briefly discussed.
ISSN:1477-9226
1477-9234
DOI:10.1039/d1dt03888e