Hollow fiber liquid-phase microextraction combined with supercritical fluid chromatography coupled to mass spectrometry for multiclass emerging contaminant quantification in water samples

The hollow fiber liquid-phase microextraction allows highly selective concentration of organic compounds that are at trace levels. The determination of those analytes through the supercritical fluid chromatography usage is associated with many analytical benefits, which are significantly increased w...

Full description

Saved in:
Bibliographic Details
Published in:Analytical and bioanalytical chemistry 2021-04, Vol.413 (9), p.2467-2479
Main Authors: Salvatierra-Stamp, Vilma del Carmen, Ceballos-Magaña, Silvia G., Pano-Farias, Norma Susana, Leyva-Morales, José Belisario, Pineda-Urbina, Kayim, Muñiz-Valencia, Roberto
Format: Article
Language:English
Subjects:
1-Octanol
Analytical Chemistry
Biochemistry
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Chromatography
Contaminants
Food Science
Ions
Laboratory Medicine
Liquid chromatography
Liquid phases
Mass spectrometry
Mass spectroscopy
Mathematical analysis
Methods
Monitoring/Environmental Analysis
Octanol
Organic compounds
Organic solvents
Polypropylene
Research Paper
Scientific imaging
Spectroscopy
Supercritical fluids
Trace levels
Wastewater
Wastewater pollution
Water analysis
Water pollution
Water sampling
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The hollow fiber liquid-phase microextraction allows highly selective concentration of organic compounds that are at trace levels. The determination of those analytes through the supercritical fluid chromatography usage is associated with many analytical benefits, which are significantly increased when it is coupled to a mass spectrometry detector, thus providing an extremely sensitive analytical technique with minimal consumption of organic solvents. On account of this, a hollow fiber liquid-phase microextraction technique in two-phase mode combined with supercritical fluid chromatography coupled to mass spectrometry was developed for quantifying 19 multiclass emerging contaminants in water samples in a total chromatographic time of 5.5 min. The analytical method used 40 μL of 1-octanol placed in the porous-walled polypropylene fiber as the acceptor phase, and 1 L of water sample was the donor phase. After extraction and quantification techniques were optimized in detail, a good determination coefficient ( r 2  > 0.9905) in the range of 0.1 to 100 μg L −1 , for most of the analytes, and an enrichment factor in the range of 7 to 28,985 were obtained. The recovery percentage (%R) and intraday precision (%RSD) were in the range of 80.80–123.40%, and from 0.48 to 16.89%, respectively. Limit of detection and quantification ranged from 1.90 to 35.66 ng L −1 , and from 3.41 to 62.11 ng L −1 , respectively. Finally, the developed method was successfully used for the determination of the 19 multiclass emerging contaminants in superficial and wastewater samples.
ISSN:1618-2642
1618-2650
DOI:10.1007/s00216-021-03202-0