Isolable dicarbon stabilized by a single phosphine ligand

In contrast to naturally occurring F , O and N , diatomic C is an intriguing species that has only been observed indirectly in the gas phase, and because of its high reactivity has eluded isolation in the condensed phase. It has previously been stabilized in L→C ←L compounds but the bonding situatio...

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Bibliographic Details
Published in:Nature chemistry 2021-01, Vol.13 (1), p.89-93
Main Authors: Leung, Tsz-Fai, Jiang, Dandan, Wu, Ming-Chun, Xiao, Dengmengfei, Ching, Wei-Min, Yap, Glenn P A, Yang, Tao, Zhao, Lili, Ong, Tiow-Gan, Frenking, Gernot
Format: Article
Language:English
Subjects:
Ambient temperature
Analytical chemistry
Chemical analysis
Chemical bonds
Hydrogen bonds
Ligands
Phosphine
Phosphines
Quantum chemistry
Reactivity
Vapor phases
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Summary:In contrast to naturally occurring F , O and N , diatomic C is an intriguing species that has only been observed indirectly in the gas phase, and because of its high reactivity has eluded isolation in the condensed phase. It has previously been stabilized in L→C ←L compounds but the bonding situation of the central C in this motif differs remarkably from that of free C . Here we have prepared and structurally characterized diatomic C as a monoligated complex L→C using a bulky phosphine ligand bearing two imidazolidin-2-iminato groups (L is (NHC =N) (CH )P, where NHC is an N-heterocyclic carbene). The compound is stable in solution at ambient temperature and has also been isolated in the solid state. Reactivity studies, in combination with quantum chemical analysis, suggest that the two carbon atoms of the L→C complex both have carbene character. The complex underwent intermolecular C-H bond activation upon thermolysis and exhibited hydroalkoxylation-like reactivity with methanol.
ISSN:1755-4330
1755-4349
DOI:10.1038/s41557-020-00579-w