Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF3SO2Na

This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac)3. The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance.

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2020-09, Vol.18 (33), p.6483-6486
Main Authors: Long, Wenhao, Lian, Pengcheng, Li, Jingjing, Wan, Xiaobing
Format: Article
Language:English
Subjects:
Aliphatic compounds
Alkenes
Catalysts
Chemical synthesis
Functional groups
Substrates
Online Access:Get full text
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Description
Summary:This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac)3. The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance.
ISSN:1477-0520
1477-0539
DOI:10.1039/d0ob01322f