A large dinuclear Fe() triple helicate demonstrating a two-step spin crossover

Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe( ii ) triple helicate system to exhibit spin crossover-and also a rare example of a 273° helical twist using aromatic spacers-is presented, with exploration of the two-step spi...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-08, Vol.56 (62), p.8838-8841
Main Authors: Howard-Smith, Kyle J, Craze, Alexander R, Zenno, Hikaru, Yagyu, Junya, Hayami, Shinya, Li, Feng
Format: Article
Language:English
Subjects:
Crossovers
Crystallography
Electron spin
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Summary:Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe( ii ) triple helicate system to exhibit spin crossover-and also a rare example of a 273° helical twist using aromatic spacers-is presented, with exploration of the two-step spin-transition observed. The largest reported dinuclear Fe( ii ) triple helicate system to exhibit spin crossover is presented, with exploration of the two-step spin-transition.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc03708g