Templated Growth of a Homochiral Thin Film Oxide

Chiral surfaces are of growing interest for enantioselective adsorption and reactions. While metal surfaces can be prepared with a wide range of chiral surface orientations, chiral oxide surface preparation is more challenging. We demonstrate the chirality of a metal surface can be used to direct th...

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Bibliographic Details
Published in:ACS nano 2020-04, Vol.14 (4), p.4682-4688
Main Authors: Schilling, Alex C, Therrien, Andrew J, Hannagan, Ryan T, Marcinkowski, Matthew D, Kress, Paul L, Patel, Dipna A, Balema, Tedros A, Larson, Amanda M, Lucci, Felicia R, Coughlin, Benjamin P, Zhang, Renqin, Thuening, Theodore, Çınar, Volkan, McEwen, Jean-Sabin, Gellman, Andrew J, Sykes, E. Charles H
Format: Article
Language:English
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Summary:Chiral surfaces are of growing interest for enantioselective adsorption and reactions. While metal surfaces can be prepared with a wide range of chiral surface orientations, chiral oxide surface preparation is more challenging. We demonstrate the chirality of a metal surface can be used to direct the homochiral growth of a thin film chiral oxide. Specifically, we study the chiral “29” copper oxide, formed by oxidizing a Cu(111) single crystal at 650 K. Surface structure spread single crystals, which expose a continuous distribution of surface orientations as a function of position on the crystal, enable us to systematically investigate the mechanism of chirality transfer between the metal and the surface oxide with high-resolution scanning tunneling microscopy. We discover that the local underlying metal facet directs the orientation and chirality of the oxide overlayer. Importantly, single homochiral domains of the “29” oxide were found in areas where the Cu step edges that templated growth were ≤20 nm apart. We use this information to select a Cu­(239 241 246) oriented single crystal and demonstrate that a “29” oxide surface can be grown in homochiral domains by templating from the subtle chirality of the underlying metal crystal. This work demonstrates how a small degree of chirality induced by slight misorientation of a metal surface (∼1 sites/20 nm2) can be amplified by oxidation to yield a homochiral oxide with a regular array of chiral oxide pores (∼75 sites/20 nm2). This offers a general approach for making chiral oxide surfaces via oxidation of an appropriately “miscut” metal surface.
ISSN:1936-0851
1936-086X
DOI:10.1021/acsnano.0c00398