A homochiral Zn-Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

Both second-order nonlinear optical and single-molecule magnet properties are observed in a novel 1D homochiral Zn-Dy heterometallic left-handed helical chain complex (1) without chiral ligands, which evolves from a Zn3Dy2 pentanuclear cluster complex (2), thanks to the structural guiding role of pe...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2018-11, Vol.54 (95), p.13379-13382
Main Authors: Liu, Cai-Ming, Zhang, De-Qing, Xiong, Ren-Gen, Hao, Xiang, Zhu, Dao-Ben
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Both second-order nonlinear optical and single-molecule magnet properties are observed in a novel 1D homochiral Zn-Dy heterometallic left-handed helical chain complex (1) without chiral ligands, which evolves from a Zn3Dy2 pentanuclear cluster complex (2), thanks to the structural guiding role of perchlorate anions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc07468b