Synthesis of the novel MOF hcp UiO-66 employing ionic liquids as a linker precursor

By using a terephthalate containing ionic liquid, a new metal-organic framework, hcp UiO-66, comprising (Zr12O8(OH)14) double clusters and terephthalate ligands has been synthesized. The hydrothermal synthesis of hcp UiO-66 might help to establish metal-organic frameworks for industrial scale applic...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018-10, Vol.47 (41), p.14426-14430
Main Authors: Ermer, Matthias, Mehler, Julian, Kriesten, Martin, Avadhut, Yamini S, Schulz, Peter S, Hartmann, Martin
Format: Article
Language:English
Subjects:
Crystal structure
Hydrothermal crystal growth
Infrared spectroscopy
Ionic liquids
Ions
Metal-organic frameworks
NMR spectroscopy
Solvents
Spectrum analysis
Synthesis
Terephthalate
Thermogravimetric analysis
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Summary:By using a terephthalate containing ionic liquid, a new metal-organic framework, hcp UiO-66, comprising (Zr12O8(OH)14) double clusters and terephthalate ligands has been synthesized. The hydrothermal synthesis of hcp UiO-66 might help to establish metal-organic frameworks for industrial scale applications.
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt02999g