Quantification of humic acids in surface water: effects of divalent cations, pH, and filtration

Humic acids (HAs) content of raw water is an important analytical parameter in water treatment facilities because HAs in the presence of chlorine may lead to the formation of dangerous by-products (e.g., trihalomethanes). The concentration of HAs in water is not directly accessible by common analyti...

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Bibliographic Details
Published in:Journal of environmental monitoring 2009-02, Vol.11 (2), p.377-382
Main Authors: Rodrigues, Alexandrina, Brito, António, Janknecht, Peter, Proença, Maria Fernanda, Nogueira, Regina
Format: Article
Language:English
Subjects:
Carbon - chemistry
Cations, Divalent - chemistry
Chemistry Techniques, Analytical - methods
Environmental Monitoring - methods
Filtration
Humic Substances - analysis
Hydrogen-Ion Concentration
Sensitivity and Specificity
Spectrophotometry, Ultraviolet
Water - analysis
Water Pollutants, Chemical - analysis
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Summary:Humic acids (HAs) content of raw water is an important analytical parameter in water treatment facilities because HAs in the presence of chlorine may lead to the formation of dangerous by-products (e.g., trihalomethanes). The concentration of HAs in water is not directly accessible by common analytical methods due to their heterogeneous chemical structure. The aim of this study was to compare two methods to assess humic acids (HAs) in surface water namely absorbance of ultraviolet light at 254 nm (UV(254)) and total organic carbon (TOC), as well as to evaluate the effects of calcium and magnesium concentrations, pH and sample filtration on the methods' results. An aqueous solution of a commercial HA with 10 mg L(-1) was used in the present work. Quantification of the HA was carried out by both UV(254) and TOC (combustion-infrared method) measurements. UV(254) results were converted to TOC using a calibration curve. The effects of calcium (0-136.3 mg L(-1)) and magnesium (0-34.5 mg L(-1)) concentrations, pH (4.0, 7.0 and 9.0) and sample filtration on UV(254) and TOC measurements of the HA suspension were evaluated. More accurate TOC values of HA suspensions were obtained by the combustion-infrared method than by the UV(254) absorbance method. The higher differences of TOC values between unfiltered and filtered samples were detected in the presence of calcium at pH 9.0 using the spectrophotometric method.
ISSN:1464-0325
1464-0333
DOI:10.1039/b811942b