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A three-dimensional cubic halogen-bonded network

The rational, deliberate design of supramolecular architectures is of great importance for the discovery of complex materials. A three-dimensional cubic halogen-bonded network has been prepared by combination of an octahedral metal-containing halogen bond acceptor and a linear ditopic donor. This ma...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (32), p.3974-3976
Main Authors: Pfrunder, Michael C, Brock, Aidan J, Brown, Joshua J, Grosjean, Arnaud, Ward, John, McMurtrie, John C, Clegg, Jack K
Format: Article
Language:English
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Summary:The rational, deliberate design of supramolecular architectures is of great importance for the discovery of complex materials. A three-dimensional cubic halogen-bonded network has been prepared by combination of an octahedral metal-containing halogen bond acceptor and a linear ditopic donor. This material displays α-Po pcu topology and is seven-fold interpenetrated. This is the first neutral, metal-containing three-dimensional halogen-bonded network to be reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc02178c