Thermal decomposition pathways of nitro-functionalized metal-organic frameworks

The decomposition behavior of high energy metal-organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both t...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017-07, Vol.53 (55), p.7808-7811
Main Authors: McDonald, Kyle A, Ko, Nakeun, Noh, Kyungkyou, Bennion, Jonathan C, Kim, Jaheon, Matzger, Adam J
Format: Article
Language:English
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Summary:The decomposition behavior of high energy metal-organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both the structural metal and intimate mixing are found to be critical.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc03354k