Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes

Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η -C Me )(NMe ) Cl ] (n = 3, 1) with amine-borane adducts NHR BH (R = Me , HtBu). The reactions involve the formation of amidoborane ligands with ZrH-B interactions which readily undergo β-...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2017-04, Vol.46 (16), p.5138-5142
Main Authors: Greño, Maider, Mena, Miguel, Pérez-Redondo, Adrián, Yélamos, Carlos
Format: Article
Language:English
Subjects:
Adducts
Formations
Hydrides
Ligands
Zirconium hydrides
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Summary:Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η -C Me )(NMe ) Cl ] (n = 3, 1) with amine-borane adducts NHR BH (R = Me , HtBu). The reactions involve the formation of amidoborane ligands with ZrH-B interactions which readily undergo β-hydride elimination to give hydride functions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt00857k