Defluoridation of drinking water using a new flow column-electrocoagulation reactor (FCER) - Experimental, statistical, and economic approach

A new batch, flow column electrocoagulation reactor (FCER) that utilises a perforated plate flow column as a mixer has been used to remove fluoride from drinking water. A comprehensive study has been carried out to assess its performance. The efficiency of fluoride removal (R%) as a function of key...

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Bibliographic Details
Published in:Journal of environmental management 2017-07, Vol.197, p.80-88
Main Authors: Hashim, Khalid S., Shaw, Andy, Al Khaddar, Rafid, Ortoneda Pedrola, Montserrat, Phipps, David
Format: Article
Language:English
Subjects:
Drinking Water
Electrochemistry
Electrocoagulation
Electrodes
Electrolysis
Fluoride
Hydrogen-Ion Concentration
Modelling
Operating cost
Perforated electrodes
SEM
Water Purification
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Summary:A new batch, flow column electrocoagulation reactor (FCER) that utilises a perforated plate flow column as a mixer has been used to remove fluoride from drinking water. A comprehensive study has been carried out to assess its performance. The efficiency of fluoride removal (R%) as a function of key operational parameters such as initial pH, detention time (t), current density (CD), inter-electrode distance (ID) and initial concentration (C0) has been examined and an empirical model has been developed. A scanning electron microscopy (SEM) investigation of the influence of the EC process on morphology of the surface of the aluminium electrodes, showed the erosion caused by aluminium loss. A preliminary estimation of the reactor's operating cost is suggested, allowing for the energy from recycling of hydrogen gas hydrogen gas produced amount. The results obtained showed that 98% of fluoride was removed within 25 min of electrolysis at pH of 6, ID of 5 mm, and CD of 2 mA/cm2. The general relationship between fluoride removal and operating parameters could be described by a linear model with R2 of 0.823. The contribution of the operating parameters to the suggested model followed the order: t > CD > C0 > ID > pH. The SEM images obtained showed that, after the EC process, the surface of the anodes, became non-uniform with a large number of irregularities due to the generation of aluminium hydroxides. It is suggested that these do not materially affect the performance. A provisional estimate of the operating cost was 0.379 US $/m3. Additionally, it has been found that 0.6 kW/m3 is potentially recoverable from the H2 gas. Fluoride removal at different initial concentrations. [Display omitted] •The new reactor, FCER, removed 98% of fluoride.•Performance of FECR, in terms of fluoride removal, was modelled with R2 of 0.823.•FCER emits H2 gas enough to produce energy of 0.6 kW/m3.•SEM images showed many dents on the anode due to the production of Al hydroxides.•FCER required 0.379 US $/m3 to remove 20 mg/L of fluoride from drinking water.
ISSN:0301-4797
1095-8630
DOI:10.1016/j.jenvman.2017.03.048