Odd–Even Effect on Nematic SmAd Phase Boundary and SmAd Structure in Homologous Binary Systems of Cyanobiphenyl Mesogens: 4‑Alkyl-4′-cyanobiphenyl (nCB) and 4‑Alkoxy-4′-cyanobiphenyl (nOCB)
Phase behaviors of two homologous binary systems of 4-alkyl-4′-cyanobiphenyl (nCB, n being the number of carbon atoms in the alkyl chain) and 4-alkoxy-4′-cyanobiphenyl (nOCB) were investigated. Their phase diagrams were drawn against an averaged chain length, n*. The phase boundary curves between ne...
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| Published in: | The journal of physical chemistry. B 2017-02, Vol.121 (6), p.1438-1447 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | eng |
| Online Access: | Get full text |
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| Summary: | Phase behaviors of two homologous binary systems of 4-alkyl-4′-cyanobiphenyl (nCB, n being the number of carbon atoms in the alkyl chain) and 4-alkoxy-4′-cyanobiphenyl (nOCB) were investigated. Their phase diagrams were drawn against an averaged chain length, n*. The phase boundary curves between neamtic (N) and smectic Ad (SmAd) phases in nCB/mCB (n = 3–6; m = 8, 9) binary systems were classified into four depending on four combinations of even- and odd-numbered n and m; even/even, odd/even, even/odd, and odd/odd. The similar odd–even effect was confirmed for nOCB/mOCB (n = 5, 6; m = 8, 9) binary systems. To elucidate the odd–even effect on the phase diagrams, the SmAd structures were investigated through an analysis of n (n*) dependence of the layer spacing of the SmAd structure, d SmAd, of neat nCB (n = 8–10), neat nOCB (n = 8–10), and nCB/8CB (n = 0–7) binary mixtures. The odd–even effect, the behavior of 0CB/8CB system, and the difference between nCB and nOCB were clarified based on their SmAd structures. |
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| ISSN: | 1520-6106 1520-5207 |