Synthesis and Reactions of Allylic, Allenic, Vinylic, and Arylmetal Reagents from Halides and Esters via Transient Organopalladium Intermediates

A significant number of vinylmetal and 1,2-vinyldimetal compounds have been prepared by palladium-catalyzed additions of organometal or diorganodimetal compounds to alkynes. Marshall surveys reactions involving an initial oxidative addition of a Pd catalyst to a C-X bond.

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Bibliographic Details
Published in:Chemical reviews 2000-08, Vol.100 (8), p.3163-3186
Main Author: Marshall, James A
Format: Article
Language:English
Subjects:
Chemical bonds
Chemical reactions
Metals
Organic chemistry
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Summary:A significant number of vinylmetal and 1,2-vinyldimetal compounds have been prepared by palladium-catalyzed additions of organometal or diorganodimetal compounds to alkynes. Marshall surveys reactions involving an initial oxidative addition of a Pd catalyst to a C-X bond.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr000003u