Intercalation of primary alkylamines into lambda-zirconium phosphate: lambda-type materials with extended interlayer separation

The intercalation of primary alkylamine into Zirconium phosphate (ZrP) is very powerful synthetic tool to facilitate the diffusion and incorporation of huge organic and inorganic molecules inside the interlayer gallery of ZrP. The intercalation of primary alkylamine into α- and γ-type ZrP is well st...

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Bibliographic Details
Published in:Journal of porous materials 2016-12, Vol.23 (6), p.1519-1526
Main Authors: Alhendawi, Hussein, Brunet, Ernesto, Hammouda, Huda, Payán, Elena Rodríguez, Juanes, Olga
Format: Article
Language:English
Subjects:
Alkylamines
Catalysis
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Galleries
Intercalation
Interlayers
Molecular chains
Organic chemistry
Phosphates
Physical Chemistry
Porous materials
Separation
Zirconium
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Summary:The intercalation of primary alkylamine into Zirconium phosphate (ZrP) is very powerful synthetic tool to facilitate the diffusion and incorporation of huge organic and inorganic molecules inside the interlayer gallery of ZrP. The intercalation of primary alkylamine into α- and γ-type ZrP is well studied. However, the intercalation chemistry of λ-ZrP has never been investigated until now. It has been found that λ-type materials with extended interlayer separation can be obtained by intercalation of primary alkylamines (C n H 2n+1 NH 2 ; n = 1, 2, 4 and 6) into the interlayer gallery of λ-ZrP.
ISSN:1380-2224
1573-4854
DOI:10.1007/s10934-016-0212-1