Radical Enantioselective C(sp3)−H Functionalization

Radical style: Several breakthroughs have recently been achieved in enantioselective C(sp3)−H functionalization through radical activation. These new strategies show how radical chemistry can be used to convert alkanes into functionalized chiral molecules (see scheme; HAT=hydrogen atom transfer).

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2017-01, Vol.56 (1), p.49-51
Main Authors: Lu, Qingquan, Glorius, Frank
Format: Article
Language:English
Subjects:
Alkanes
asymmetric synthesis
copper catalysis
C−H functionalization
Enantiomers
photoredox catalysis
radical activation
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Description
Summary:Radical style: Several breakthroughs have recently been achieved in enantioselective C(sp3)−H functionalization through radical activation. These new strategies show how radical chemistry can be used to convert alkanes into functionalized chiral molecules (see scheme; HAT=hydrogen atom transfer).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201609105