Ru-Catalyzed highly site-selective C–H bond arylation of 9-(pyrimidin-2-yl)-9H-carbazole

We describe here an efficient ruthenium-catalyzed C–H bond ortho -arylation of 9-(pyrimidin-2-yl)-9 H -carbazole by using boronic acids. This methodology exhibits excellent and high site-selectivity, functional group tolerance and was found to give the desired product in moderate to good yields.

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Bibliographic Details
Published in:RSC advances 2016-01, Vol.6 (59), p.54431-54434
Main Authors: Harsha Vardhan Reddy, K., Kumar, R. Uday, Reddy, V. Prakash, Satish, G., Nanubolu, Jagadeesh Babu, Nageswar, Y. V. D.
Format: Article
Language:English
Subjects:
Bonding
Functional groups
Methodology
Tolerances
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Description
Summary:We describe here an efficient ruthenium-catalyzed C–H bond ortho -arylation of 9-(pyrimidin-2-yl)-9 H -carbazole by using boronic acids. This methodology exhibits excellent and high site-selectivity, functional group tolerance and was found to give the desired product in moderate to good yields.
ISSN:2046-2069
2046-2069
DOI:10.1039/C6RA09825H