The Properties of the Water-Soluble Hydroxy-Polyhydroxy fullerenes in Auto-Oxidation Reactions Epinephrine

The Properties of the Water-Soluble Hydroxy-Polyhydroxy fullerenes in Auto-Oxidation Reactions Epinephrine

The studied of the influence of fuller enoles on adrenaline auto-oxidation reaction by optical and theoretical methods was carried out in this work. It was shown that fullerenols at concentrations from 0.0005 mg/ml to 0.5 mg/ml exhibits prooxidant activity and accelerates autoxidation reaction of ad...

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Bibliographic Details
Published in:Journal of Siberian Federal University. Chemistry 2015-01, Vol.8 (4), p.533-540
Main Authors: Yaykova, Olga A, Tomilin, Felix N, Dubinina, Irina A, Kuzubov, Alexander A, Dudnik, Alexander I, Vnukova, Natalia G, Ovchinnikov, Sergey G, Churilov, Grigory N
Format: Article
Language:eng ; rus
Subjects:
Autoxidation
Density
Epinephrine
Fullerenes
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Summary:The studied of the influence of fuller enoles on adrenaline auto-oxidation reaction by optical and theoretical methods was carried out in this work. It was shown that fullerenols at concentrations from 0.0005 mg/ml to 0.5 mg/ml exhibits prooxidant activity and accelerates autoxidation reaction of adrenaline. The suggested scheme of auto-oxidation reaction, which explained by energy advantage under transferring electron from the molecule of adrenaline to fullerenol by density functional method B3LYP/6-31(p,d).
ISSN:1998-2836
2313-6049