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Monitoring organic reactions by UF-NMR spectroscopy
Standard 2D NMR experiments suffer from the many t1 increments needed for spectra with sufficient digital resolution in the indirect dimension. Despite the different methodological approaches to overcome this problem, these increments have prevented studies of fast reactions. The development of ultr...
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| Published in: | Magnetic resonance in chemistry 2015-11, Vol.53 (11), p.952-970 |
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| Main Authors: | , , , , , |
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| cites | cdi_FETCH-LOGICAL-c4530-c3f187af59c1a13d0e95143154937f28afb53a84b5b37d20d55d1863dc2c27853 |
| container_end_page | 970 |
| container_issue | 11 |
| container_start_page | 952 |
| container_title | Magnetic resonance in chemistry |
| container_volume | 53 |
| creator | Herrera, Antonio Fernández-Valle, Encarnación Martínez-Álvarez, Roberto Molero-Vílchez, Dolores Pardo-Botero, Zulay D. Sáez-Barajas, Elena |
| description | Standard 2D NMR experiments suffer from the many t1 increments needed for spectra with sufficient digital resolution in the indirect dimension. Despite the different methodological approaches to overcome this problem, these increments have prevented studies of fast reactions. The development of ultrafast NMR (UF‐NMR) has decisively speeded up the time scale of standard NMR to allow the study of organic reactions as they happen in real time to reveal mechanistic details. This mini‐review summarizes the results achieved in monitoring organic reactions through this exciting technique. Copyright © 2015 John Wiley & Sons, Ltd.
Ultrafast NMR has undoubtedly opened up new perspectives in monitoring dynamic systems as they happen in real time. It has permitted to study in‐depth fast organic reactions and transient species participating in their mechanisms. In the present review are shown some results that highlight the potential of the methodology. |
| doi_str_mv | 10.1002/mrc.4240 |
| format | article |
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Ultrafast NMR has undoubtedly opened up new perspectives in monitoring dynamic systems as they happen in real time. It has permitted to study in‐depth fast organic reactions and transient species participating in their mechanisms. In the present review are shown some results that highlight the potential of the methodology.</description><subject>2D NMR spectroscopy</subject><subject>Chemical reactions</subject><subject>Dynamical systems</subject><subject>Dynamics</subject><subject>Monitoring</subject><subject>Nuclear magnetic resonance</subject><subject>Real time</subject><subject>real-time monitoring</subject><subject>Spectra</subject><subject>ultrafast NMR</subject><issn>0749-1581</issn><issn>1097-458X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqN0EFrGzEQhmFRGho3LfQXlIVeetl0pNGspGNxGjcQOyUkJDeh1WrDpvbKlda0_vddEyeFQiCnuTy8MB9jHzgccwDxZZX8sRQSXrEJB6NKSfr2NZuAkqbkpPkhe5vzPQAYo_ANOxRkjCaoJgznse-GmLr-rojpzvWdL1Jwfuhin4t6W1yflov5ZZHXwQ8pZh_X23fsoHXLHN7v7xG7Pv12Nf1enl_MzqZfz0svCaH02HKtXEvGc8exgWCIS-QkDapWaNfWhE7LmmpUjYCGqOG6wsYLL5QmPGKfH7rrFH9tQh7sqss-LJeuD3GTLVcKUKCu4AVUEHFBSo_003_0Pm5SPz6yU1IAVYj_gn58OqfQ2nXqVi5tLQe729yOm9vd5iP9uA9u6lVonuDjyCMoH8Dvbhm2z4bs_HK6D-59l4fw58m79NNWChXZm8XMygU_mf44ubIz_AvYY5Y4</recordid><startdate>201511</startdate><enddate>201511</enddate><creator>Herrera, Antonio</creator><creator>Fernández-Valle, Encarnación</creator><creator>Martínez-Álvarez, Roberto</creator><creator>Molero-Vílchez, Dolores</creator><creator>Pardo-Botero, Zulay D.</creator><creator>Sáez-Barajas, Elena</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>K9.</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>201511</creationdate><title>Monitoring organic reactions by UF-NMR spectroscopy</title><author>Herrera, Antonio ; Fernández-Valle, Encarnación ; Martínez-Álvarez, Roberto ; Molero-Vílchez, Dolores ; Pardo-Botero, Zulay D. ; Sáez-Barajas, Elena</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4530-c3f187af59c1a13d0e95143154937f28afb53a84b5b37d20d55d1863dc2c27853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>2D NMR spectroscopy</topic><topic>Chemical reactions</topic><topic>Dynamical systems</topic><topic>Dynamics</topic><topic>Monitoring</topic><topic>Nuclear magnetic resonance</topic><topic>Real time</topic><topic>real-time monitoring</topic><topic>Spectra</topic><topic>ultrafast NMR</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Herrera, Antonio</creatorcontrib><creatorcontrib>Fernández-Valle, Encarnación</creatorcontrib><creatorcontrib>Martínez-Álvarez, Roberto</creatorcontrib><creatorcontrib>Molero-Vílchez, Dolores</creatorcontrib><creatorcontrib>Pardo-Botero, Zulay D.</creatorcontrib><creatorcontrib>Sáez-Barajas, Elena</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Magnetic resonance in chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Herrera, Antonio</au><au>Fernández-Valle, Encarnación</au><au>Martínez-Álvarez, Roberto</au><au>Molero-Vílchez, Dolores</au><au>Pardo-Botero, Zulay D.</au><au>Sáez-Barajas, Elena</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monitoring organic reactions by UF-NMR spectroscopy</atitle><jtitle>Magnetic resonance in chemistry</jtitle><addtitle>Magn. Reson. Chem</addtitle><date>2015-11</date><risdate>2015</risdate><volume>53</volume><issue>11</issue><spage>952</spage><epage>970</epage><pages>952-970</pages><issn>0749-1581</issn><eissn>1097-458X</eissn><notes>MINECO - No. CTQ2010-14936</notes><notes>istex:6973982809E826A4232A6FEFEBF33DA71E34A2F6</notes><notes>ArticleID:MRC4240</notes><notes>ark:/67375/WNG-4N1DCPDT-G</notes><notes>ObjectType-Article-2</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-3</notes><notes>content type line 23</notes><notes>ObjectType-Review-1</notes><notes>ObjectType-Article-1</notes><notes>ObjectType-Feature-2</notes><abstract>Standard 2D NMR experiments suffer from the many t1 increments needed for spectra with sufficient digital resolution in the indirect dimension. Despite the different methodological approaches to overcome this problem, these increments have prevented studies of fast reactions. The development of ultrafast NMR (UF‐NMR) has decisively speeded up the time scale of standard NMR to allow the study of organic reactions as they happen in real time to reveal mechanistic details. This mini‐review summarizes the results achieved in monitoring organic reactions through this exciting technique. Copyright © 2015 John Wiley & Sons, Ltd.
Ultrafast NMR has undoubtedly opened up new perspectives in monitoring dynamic systems as they happen in real time. It has permitted to study in‐depth fast organic reactions and transient species participating in their mechanisms. In the present review are shown some results that highlight the potential of the methodology.</abstract><cop>England</cop><pub>Blackwell Publishing Ltd</pub><pmid>25998506</pmid><doi>10.1002/mrc.4240</doi><tpages>19</tpages></addata></record> |
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| ispartof | Magnetic resonance in chemistry, 2015-11, Vol.53 (11), p.952-970 |
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| language | eng |
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| source | Wiley Online Library |
| subjects | 2D NMR spectroscopy Chemical reactions Dynamical systems Dynamics Monitoring Nuclear magnetic resonance Real time real-time monitoring Spectra ultrafast NMR |
| title | Monitoring organic reactions by UF-NMR spectroscopy |
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