Investigation on luminescence enhancement and decay characteristics of long afterglow nanophosphors for dark-vision display applications

•Synthesis and structural characterization has been performed on long afterglow SrAl2O4:Eu2+, Dy3+ nanophosphor having afterglow time of ∼12h.•Studied the effect of various fuels used for synthesis of nanophosphors on the decay and luminescence characteristics. Interestingly, afterglow times varied...

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Bibliographic Details
Published in:Applied surface science 2015-04, Vol.333, p.178-185
Main Authors: Swati, G., Chawla, S., Mishra, S., Rajesh, B., Vijayan, N., Sivaiah, B., Dhar, A., Haranath, D.
Format: Article
Language:English
Subjects:
Afterglows
Auto-combustion
Blue shift
Decomposition
Emission
Fingerprints
Illuminants
Luminescence
Maxima
Nanophosphor
Nanostructure
Photoluminescence
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Summary:•Synthesis and structural characterization has been performed on long afterglow SrAl2O4:Eu2+, Dy3+ nanophosphor having afterglow time of ∼12h.•Studied the effect of various fuels used for synthesis of nanophosphors on the decay and luminescence characteristics. Interestingly, afterglow times varied significantly with different fuels used for the synthesis of the nanophosphor.•Excitation by different illuminants has profound influence on the luminescence intensity and afterglow times of the synthesized nanophosphor.•Such studies could be guidelines for appropriate usage of nanophosphor under different lighting environment. Long afterglow SrAl2O4:Eu2+,Dy3+ nanophosphors were synthesized via a facile but effectual auto-combustion technique followed by post-annealing treatment at elevated temperatures. The influence of various fuels during synthesis and thereafter improvement in the luminescence decay characteristics under various illuminant irradiations of long afterglow nanophosphors have been reported. Extensive studies on structural, morphological and luminescent properties of the as-synthesized afterglow nanophosphors have been presented. Powder X-ray diffraction studies confirm the presence of high-purity, single-phase monoclinic nanophosphors. HRTEM investigations confirm the formation of nanophosphors of particle size less than 50nm. Photoluminescence emission is attributed to the characteristic d–f transition (4f65d1→4f7) of Eu2+ ions and was positioned at 512nm. As-synthesized nanophosphors exhibit considerable confinement effects resulting into blue shift in emission maxima as compared to their bulk counterparts. The mechanism underlined for long afterglow has been discussed using trapping–detrapping model. The nanophosphor being multifunctional finds many interesting applications including dark-vision display, energy storage, fingerprint detection, in vivo and in vitro biological staining, etc.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2015.01.135