Doping-Induced Screening of the Built-in-Field in Organic Solar Cells: Effect on Charge Transport and Recombination

We report on the effects of screening of the electric field by doping‐induced mobile charges on photocurrent collection in operational organic solar cells. Charge transport and recombination were studied using double injection (DI) and charge extraction by linearly increasing voltage (CELIV) transie...

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Bibliographic Details
Published in:Advanced energy materials 2013-03, Vol.3 (3), p.321-327
Main Authors: Armin, Ardalan, Juska, Gytis, Philippa, Bronson W., Burn, Paul L., Meredith, Paul, White, Ronald D., Pivrikas, Almantas
Format: Article
Language:English
Subjects:
bimolecular recombination
Charge
charge carrier transport
Charge transport
Collection
Doping
doping level
double injection
Electric charge
organic solar cells
Photovoltaic cells
Screening
Solar cells
Solar energy
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Summary:We report on the effects of screening of the electric field by doping‐induced mobile charges on photocurrent collection in operational organic solar cells. Charge transport and recombination were studied using double injection (DI) and charge extraction by linearly increasing voltage (CELIV) transient techniques in bulk‐heterojunction solar cells made from acceptor‐donor blends of poly(3‐n‐hexylthiophene):phenyl‐C61‐butyric acid methyl ester (P3HT:PC60BM). It is shown that the screening of the built‐in field in operational solar cells can be controlled by an external voltage while the influence on charge transport and recombination is measured. An analytical theory to extract the bimolecular recombination coefficient as a function of electric field from the injection current is also reported. The results demonstrate that the suppressed (non‐Langevin) bimolecular recombination rate and charge collection are not strongly affected by native doping levels in this materials combination. Hence, it is not necessary to reduce the level of doping further to improve the device performance of P3HT‐based solar cells. Effects of screening of the electric field by doping‐induced mobile charges on photocurrent collection in operational organic solar cells are reported. Charge transport and recombination were studied using double injection and charge extraction by linearly increasing voltage (CELIV) transient techniques. The results demonstrate that the suppressed bimolecular recombination and charge collection are not necessarily strongly affected by native doping levels.
ISSN:1614-6832
1614-6840
DOI:10.1002/aenm.201200581