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Na+ induced electric-dipole dominated transition (5D0→7F2) of Eu3+ emission in AMgPO4:Eu3+ (A=Li+, Na+, K+) phosphors
A series of Eu3+ doped (AMgPO4)1.00−x:Eu3+x (A=Li+, Na+, K+) phosphors were prepared by the solid-state method. XRD results confirm that the samples contain mixture phases of crystals. Cation effect of Li+, Na+, K+ on the PL properties of (AMgPO4)1.00−x:Eu3+x phosphors is discussed. The results indi...
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Published in: | Materials letters 2015-04, Vol.145, p.359-362 |
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Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A series of Eu3+ doped (AMgPO4)1.00−x:Eu3+x (A=Li+, Na+, K+) phosphors were prepared by the solid-state method. XRD results confirm that the samples contain mixture phases of crystals. Cation effect of Li+, Na+, K+ on the PL properties of (AMgPO4)1.00−x:Eu3+x phosphors is discussed. The results indicated that among the three cations, Na+ not only provides the most intensity of Eu3+ emission, but also produces electric-dipole dominated transition (5D0→7F2) and results to obtain the most red color. The optimized molar concentrations of Eu3+ for the three kinds of samples are 6, 8, 10%, which (NaMgPO4)0.92:Eu3+0.08 is a potential candidate as the red-emitting phosphor for UV-based white LED.
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•Eu3+ doped (AMgPO4)1.00−x:Eu3+x (A=Li+, Na+, K+) phosphors were synthesized.•Na+ induced electric-dipole dominated transition (5D0→7F2) of Eu3+.•The as-synthesized samples can be excited by 392nm near-UV light.•(NaMgPO4)0.94:Eu3+0.06 was a potential phosphor for UV-based white LED. |
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ISSN: | 0167-577X 1873-4979 |
DOI: | 10.1016/j.matlet.2015.01.095 |