Temperature-Dependent Double Isocyanide Insertion Reaction To Construct a Polycyclic Skeleton

A novel strategy to furnish selective double insertion of isocyanides with the aid of potassium tetrachloroaurate­(III) has been disclosed. This strategy provides quick access to approach a complex polycyclic skeleton in an efficient manner. Unexpected oxygen migration was also observed when the rea...

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Bibliographic Details
Published in:Organic letters 2016-02, Vol.18 (4), p.840-843
Main Authors: Tian, Yaming, Tian, Lumin, Li, Chunju, Jia, Xueshun, Li, Jian
Format: Article
Language:English
Subjects:
Catalysis
Cyanides - chemistry
Cyclization
Molecular Structure
Polycyclic Aromatic Hydrocarbons - chemical synthesis
Polycyclic Aromatic Hydrocarbons - chemistry
Temperature
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Summary:A novel strategy to furnish selective double insertion of isocyanides with the aid of potassium tetrachloroaurate­(III) has been disclosed. This strategy provides quick access to approach a complex polycyclic skeleton in an efficient manner. Unexpected oxygen migration was also observed when the reaction was conducted at a lower temperature.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.6b00131