Synthesis of silver nanoparticles by laser ablation in ethanol: A pulsed photoacoustic study

•Pulsed photoacoustic technique allowed to determine the production rate of NPs.•Pulsed photoacoustic technique allows to determine the Ag concentration in colloids.•The nanoparticles production rate drops quickly during the first laser pulses.•Nanoparticles production rate is almost constant after...

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Bibliographic Details
Published in:Applied surface science 2015-11, Vol.355, p.341-349
Main Authors: Valverde-Alva, M.A., García-Fernández, T., Villagrán-Muniz, M., Sánchez-Aké, C., Castañeda-Guzmán, R., Esparza-Alegría, E., Sánchez-Valdés, C.F., Llamazares, J.L. Sánchez, Herrera, C.E. Márquez
Format: Article
Language:English
Subjects:
Ablation
Ethanol
Ethyl alcohol
Laser ablation
Laser ablation in liquid
Lasers
Nanoparticles
Pulsed photoacoustic analysis
Silver
Synthesis
Synthesis of silver nanoparticles
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Summary:•Pulsed photoacoustic technique allowed to determine the production rate of NPs.•Pulsed photoacoustic technique allows to determine the Ag concentration in colloids.•The nanoparticles production rate drops quickly during the first laser pulses.•Nanoparticles production rate is almost constant after few hundreds of laser shots.•Photoacoustic signal amplitude was proportional to fluence on the target surface. The pulsed photoacoustic (PA) technique was used to study the synthesis by laser ablation of silver nanoparticles (Ag-NPs) in ethanol. PA technique allowed to determine the production rate per laser pulse and concentration of synthesized Ag-NPs. The samples were produced by using a pulsed Nd:YAG laser with 1064nm of wavelength and 7ns of pulse duration. The laser pulse energy varied from 10 to 100mJ. Transmission electron microscopy micrographs demonstrated that the obtained nanoparticles were spherical with an average size close to 10nm. The absorption spectra of the colloids showed a plasmon absorption peak around 400nm. The PA analyses showed a significant reduction of the production rate of Ag-NPs during the first hundreds of laser pulses. For a higher number of pulses this rate was kept almost constant. Finally, we found that the root mean square (RMS) value of the PA signal was proportional to the laser pulse fluence on the target surface. Thus PA technique was useful to monitor the ablation process.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2015.07.133