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Low platinum loading PtNPs/graphene composite catalyst with high electrocatalytic activity for dye-sensitized solar cells

Platinum nanoparticles (PtNPs)/graphene composite materials are synthesized by a controlled chemical reduction of H2PtC16 on graphene sheets. The electrocatalytic activity of a PtNPs/graphene composite counter electrode for a dye-sensitized solar cell (DSSC) is investigated. The results demonstrate...

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Published in:Chinese physics B 2012-11, Vol.21 (11), p.490-494
Main Author: 李萍剑 程凯 陈远富 王泽高 郝昕 刘竞博 贺加瑞 张万里
Format: Article
Language:English
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Summary:Platinum nanoparticles (PtNPs)/graphene composite materials are synthesized by a controlled chemical reduction of H2PtC16 on graphene sheets. The electrocatalytic activity of a PtNPs/graphene composite counter electrode for a dye-sensitized solar cell (DSSC) is investigated. The results demonstrate that the PtNPs/graphene composite has high electrocatalytic activity for the dye-sensitized solar cell. The cell employing PtNPs (1.6 wt%)/graphene counter electrode reaches an conversion efficiency (η) of 3.89% upon the excitation of 100 mW/cm2 AM 1.5 white light, which is comparable to that of the cell with a Pt-film counter electrode (7 = 3.76%). It suggests that one can use only 14% Pt content of the conventional Pt-film counter electrode to obtain a comparable conversion efficiency. It may be possible to obtain a high performance DSSC using the PtNPs/graphene composite with a very low Pt content as a counter electrode due to its simplicity, low cost, and large scalability.
ISSN:1674-1056
2058-3834
1741-4199
DOI:10.1088/1674-1056/21/11/118101