High coercivity induced by mechanical milling in cobalt ferrite powders

In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe2O4 treated by mechanical milling with different grinding balls. The cobalt ferrite nanoparticles were prepared using a simple hydrothermal method and annealed at 500°C. The non-milled sample presented coercivity of a...

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Bibliographic Details
Published in:Journal of magnetism and magnetic materials 2013-10, Vol.344, p.182-187
Main Authors: Ponce, A.S., Chagas, E.F., Prado, R.J., Fernandes, C.H.M., Terezo, A.J., Baggio-Saitovitch, E.
Format: Article
Language:English
Subjects:
(BH)max product
Annealing
Cobalt ferrite
Cobalt ferrites
Coercive force
Coercivity
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Crystallites
Exact sciences and technology
Magnetic properties and materials
Magnetic properties of nanostructures
Mechanical milling
Milling
Physics
Remanence
Saturation (magnetic)
Strain
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Summary:In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe2O4 treated by mechanical milling with different grinding balls. The cobalt ferrite nanoparticles were prepared using a simple hydrothermal method and annealed at 500°C. The non-milled sample presented coercivity of about 1.9kOe, saturation magnetization of 69.5emu/g, and a remanence ratio of 0.42. After milling, two samples attained coercivity of 4.2 and 4.1kOe, and saturation magnetization of 67.0 and 71.4emu/g respectively. The remanence ratio MR/MS for these samples increase to 0.49 and 0.51, respectively. To investigate the influence of the microstructure on the magnetic behavior of these samples, we used X-ray powder diffraction (XPD), transmission electron microscopy, and vibrating sample magnetometry. The XPD analysis by the Williamson–Hall plot was used to estimate the average crystallite size and strain induced by mechanical milling in the samples. •Magnetic behavior of milled CoFe2O4 is studied.•The coercivity is increase of about 150%.•The remanence ratio are increase to all milled samples.•The strain and pinning effects are observed in milled samples.
ISSN:0304-8853
DOI:10.1016/j.jmmm.2013.05.056