Depolarisation of light scattered by disperse systems of low-dimensional potassium polytitanate nanoparticles in the fundamental absorption band

The results of experimental studies of depolarising properties of disperse systems on the basis of potassium polytitanate nanoplatelets and nanoribbons in the visible and near-UV spectral regions are presented. It is shown that in the fundamental absorption band of the nanoparticle material the incr...

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Bibliographic Details
Published in:Quantum electronics (Woodbury, N.Y.) N.Y.), 2014-01, Vol.44 (7), p.670-674
Main Authors: Zimnyakov, D.A., Yuvchenko, S.A., Pravdin, A.B., Kochubey, V.I., Gorokhovsky, A.V., Tretyachenko, E.V., Kunitsky, A.I.
Format: Article
Language:English
Subjects:
Absorption spectra
ANISOTROPY
Beams (radiation)
depolarisation
Dielectric constant
dielectric function
DIELECTRIC MATERIALS
Disperse
DISPERSIONS
low-dimensional nanoparticles
Mathematical models
NANOPARTICLES
NANOSCIENCE AND NANOTECHNOLOGY
Nanostructure
NANOSTRUCTURES
POTASSIUM
potassium polytitanate
scattering
TITANIUM OXIDES
ULTRAVIOLET SPECTRA
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Summary:The results of experimental studies of depolarising properties of disperse systems on the basis of potassium polytitanate nanoplatelets and nanoribbons in the visible and near-UV spectral regions are presented. It is shown that in the fundamental absorption band of the nanoparticle material the increase in the depolarisation factor takes place for the radiation scattered perpendicularly to the direction of the probing beam. For nanoribbons a pronounced peak of depolarisation is observed, which is caused by the essential anisotropy of the particles shape and the peculiarities of the behaviour of the material dielectric function. The empirical data are compared with the theoretical results for 'nanodiscs' and 'nanoneedles' with the model dielectric function, corresponding to that obtained from optical constants of the titanium dioxide dielectric function.
ISSN:1063-7818
1468-4799
DOI:10.1070/QE2014v044n07ABEH015482