Enantioselective synthesis of macrolactone core of the natural product Sch725674

An enantioselective synthesis of the macrolactone core of natural product Sch725674 was accomplished from furfural. Key reactions in assembly of the macrolactone are the use of furan as a but-2-ene-dione equivalent and ring closing metathesis. [Display omitted]

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Bibliographic Details
Published in:Tetrahedron 2014-03, Vol.70 (12), p.2096-2101
Main Authors: Sunnam, Sunil Kumar, Prasad, Kavirayani R.
Format: Article
Language:English
Subjects:
Assembly
Equivalence
Furans
Furfural
Macrolide
Metathesis
Natural products
Sch725674
Synthesis (chemistry)
Tetrahedrons
Total synthesis
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Description
Summary:An enantioselective synthesis of the macrolactone core of natural product Sch725674 was accomplished from furfural. Key reactions in assembly of the macrolactone are the use of furan as a but-2-ene-dione equivalent and ring closing metathesis. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2014.02.008