Highly functionalised cyclohexa-1,3-dienes by sulfonyl Nazarov reagents

The Hayashi–Jørgensen organocatalyst has made possible a sulfonyl Nazarov analogue reagent to give a Diels–Alder reaction at the double bond, without involving the activated methylene affording chiral highly functionalised cyclohexa-1,3-dienes. [Display omitted]

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Bibliographic Details
Published in:Tetrahedron 2014-07, Vol.70 (29), p.4386-4394
Main Authors: Peña, Javier, Moro, Rosalina F., Marcos, Isidro S., Sanz, F., Díez, David
Format: Article
Language:English
Subjects:
Activated
Analogue
Asymmetric Diels–Alder
Bonding
Cyclohexa-1,3-dienes
Diels-Alder reactions
Hayashi–Jørgensen organocatalyst
Methylene
Nazarov reagents
Sulfones
Tetrahedrons
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Description
Summary:The Hayashi–Jørgensen organocatalyst has made possible a sulfonyl Nazarov analogue reagent to give a Diels–Alder reaction at the double bond, without involving the activated methylene affording chiral highly functionalised cyclohexa-1,3-dienes. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2014.04.076