Allylation of 1-phenyl-1-propyne with N- and O-pronucleophiles using polymer supported triphenylphosphine palladium complex as a heterogeneous and recyclable catalyst

Simple methodology for the allylation of various N- and O-pronucleophiles with 1-phenyl-1-propyne as an allylating agent, using PS-TPP-Pd (polymer supported triphenylphosphine palladium) as a highly active heterogeneous recyclable catalyst has been developed. The protocol is applicable for a wide va...

Full description

Saved in:
Bibliographic Details
Published in:Tetrahedron letters 2011-10, Vol.52 (43), p.5676-5679
Main Authors: Wagh, Yogesh S., Sawant, Dinesh N., Dhake, Kishor P., Deshmukh, Krishna M., Bhanage, Bhalchandra M.
Format: Article
Language:English
Subjects:
Alkynes
Allyl compounds
Allylation
Amines
Carboxylic acids
Catalysis
Catalysts
Catalysts: preparations and properties
Catalytic activity
Catalytic reactions
Chemical reactions
Chemistry
Exact sciences and technology
General and physical chemistry
Heterogeneous catalyst
Palladium
Pronucleophiles
Tetrahedrons
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Simple methodology for the allylation of various N- and O-pronucleophiles with 1-phenyl-1-propyne as an allylating agent, using PS-TPP-Pd (polymer supported triphenylphosphine palladium) as a highly active heterogeneous recyclable catalyst has been developed. The protocol is applicable for a wide variety of hindered and functionalized aromatic amines, alcohols, and carboxylic acids. The catalyst exhibited remarkable catalytic activity for five consecutive recycles.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2011.08.099