Late season mobilization of trace metals in two small Alaskan arctic watersheds as a proxy for landscape scale permafrost active layer dynamics

Increasing air temperatures in the Arctic have the potential to degrade permafrost and promote the downward migration of the seasonally thawed active layer into previously frozen material. This may expose frozen soils to mineral weathering that could affect the geochemical composition of surface wat...

Full description

Saved in:
Bibliographic Details
Published in:Chemical geology 2014-08, Vol.381, p.180-193
Main Authors: Barker, Amanda J., Douglas, T.A., Jacobson, A.D., McClelland, J.W., Ilgen, A.G., Khosh, M.S., Lehn, G.O., Trainor, T.P.
Format: Article
Language:eng
Subjects:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Increasing air temperatures in the Arctic have the potential to degrade permafrost and promote the downward migration of the seasonally thawed active layer into previously frozen material. This may expose frozen soils to mineral weathering that could affect the geochemical composition of surface waters. Determining watershed system responses to drivers such as a changing climate relies heavily on understanding seasonal controls on freshwater processes. The majority of studies on elemental concentrations in Arctic river systems have focused on sampling only from spring snowmelt to the summer season. Consequently, there remains a limited understanding of surface water geochemistry, particularly with respect to trace metals, during late fall and early winter. To examine the variability of metal concentrations as a function of seasonality, we measured trace metal concentrations from spring melt to fall freeze-up in 2010 in two high Arctic watersheds: Imnavait Creek, North Slope, Alaska and Roche Mountanee Creek, Brooks Range, Alaska. We focused on aluminum (Al), barium (Ba), iron (Fe), manganese (Mn), nickel (Ni) and zinc (Zn). Concentrations of ‘dissolved’ (
ISSN:0009-2541
1872-6836