In Situ Study of Model Organic Friction Modifiers Using Liquid Cell AFM: Self-Assembly of Octadecylamine

Liquid cell AFM has been applied to study in situ the formation and properties of self-assembled films formed on mica surfaces by octadecylamine from alkane solution. Mica surfaces immersed in hexadecane or dodecane at room temperature show no identifiable surface films. However, when octadecylamine...

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Bibliographic Details
Published in:Tribology letters 2015-06, Vol.58 (3), p.1-15, Article 39
Main Authors: Campen, S., Green, J. H., Lamb, G. D., Spikes, H. A.
Format: Article
Language:English
Subjects:
Alkanes
Atomic force microscopy
Boundaries
Chemistry and Materials Science
Contact
Corrosion and Coatings
Depletion
Dodecane
Hexadecane
Islands
Liquids
Materials Science
Mathematical models
Mica
Nanotechnology
Original Paper
Physical Chemistry
Self assembly
Surfaces and Interfaces
Theoretical and Applied Mechanics
Thin Films
Tribology
Van der Waals forces
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Summary:Liquid cell AFM has been applied to study in situ the formation and properties of self-assembled films formed on mica surfaces by octadecylamine from alkane solution. Mica surfaces immersed in hexadecane or dodecane at room temperature show no identifiable surface films. However, when octadecylamine solution is injected into the cell, a boundary film forms almost immediately. This film takes the form of irregular islands of mean diameter approximately 1–3 µm and thickness typically 1.5 nm when measured in contact mode. These islands are believed to correspond to patches of vertically oriented but tilted octadecylamine or ammonium salt held together primarily by van der Waals forces between adjacent alkyl chains. These films are quite labile in that during scanning of the tip in both tapping mode and contact mode changes to the shape of the islands take place, including consolidation of the island density in the scanned region and depletion from around this area. In situ experiments in which the temperature of the cell is varied over time show that the initially formed islands disappear at a temperature of ca. 35 °C but are reformed when the cell is re-cooled. Similar tests on samples that remain immersed in solution for extended periods show more stable films, with islands being lost only above about 50–60 °C. The work shows that liquid cell AFM has great promise for studying the formation and properties of the boundary films formed by organic friction modifiers.
ISSN:1023-8883
1573-2711
DOI:10.1007/s11249-015-0514-5