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Development of green light filters based on high-resistance oxide glasses colored by transition elements

Glasses in the system Al 2 O 3 –P 2 O 5 –SiO 2 , which are suitable for the green light filters in traffic signal lights, were investigated. The glasses were required to satisfy the following requirements: transmission band maximum at λ max  = 500 nm high heat-resistance, and low CLTE — (41 – 49) × ...

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Bibliographic Details
Published in:Glass and ceramics 2012-05, Vol.69 (1-2), p.50-54
Main Authors: Bogomolova, L. D., Zhachkin, V. A., Pavlushkina, T. K.
Format: Article
Language:English
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Summary:Glasses in the system Al 2 O 3 –P 2 O 5 –SiO 2 , which are suitable for the green light filters in traffic signal lights, were investigated. The glasses were required to satisfy the following requirements: transmission band maximum at λ max  = 500 nm high heat-resistance, and low CLTE — (41 – 49) × 10 –7  K –1 . Transition elements served as colorants; they were introduced into the batch as the oxides TiO 2 , V 2 O 5 , CuO, and MoO 3 in amounts 1 wt.%, as well as their pairs in different combinations. The EPR and optical spectra were investigated. It was shown that glass with the composition (wt.%) 55 P 2 O 5 , 17.1 Al 2 O 3 , 20 SiO 2 , 1.5 La 2 O 3 , 2 ZrO 2 , 2.5 B 2 O 3 , 1.5 MoO 3 , and 0.5 CuO can be recommended for use as heat-resistant green light filters.
ISSN:0361-7610
1573-8515
DOI:10.1007/s10717-012-9412-6