Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)

Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)

Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.

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Bibliographic Details
Published in:Journal of organic chemistry 2015-01, Vol.80 (2), p.1214-1220
Main Authors: Zhou, Shao-Fang, Li, Da-Peng, Liu, Kui, Zou, Jian-Ping, Asekun, Olayinka Taiwo
Format: Article
Language:eng
Subjects:
Alkenes - chemistry
Manganese - chemistry
Molecular Structure
Organophosphorus Compounds - chemistry
Phosphites - chemistry
Phosphorylation
Styrenes - chemistry
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Description
Summary:Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
ISSN:0022-3263
1520-6904