Synthesis, structure and properties of ethyl naphth[2,3-f]isoindole-1-carboxylate

Ethyl 12-oxo-4,11-dihydro-4,11-ethanonaphth[2,3-f]isoind ole-1-carboxylate (2) was prepared from 7-tert-butoxynorbornadiene and quantitatively converted to ethyl naphth[2,3-f]isoindole-1-carboxylate (3) by the thermal or photochemical cheletropic reaction. Ethyl naphth[2,3-f]isoindole-1-carboxylate...

Full description

Saved in:
Bibliographic Details
Published in:RSC advances 2013-01, Vol.3 (9), p.3006-3016
Main Authors: Seike, Aya, Yamagami, Kaoru, Kakitani, Yoshimasa, Kuwajima, Miki, Uoyama, Hiroki, Nagaoka, Shin-ichi, Nakae, Takahiro, Mori, Shigeki, Okujima, Tetsuo, Uno, Hidemitsu
Format: Article
Language:English
Subjects:
Derivatives
Photochemical
Synthesis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Ethyl 12-oxo-4,11-dihydro-4,11-ethanonaphth[2,3-f]isoind ole-1-carboxylate (2) was prepared from 7-tert-butoxynorbornadiene and quantitatively converted to ethyl naphth[2,3-f]isoindole-1-carboxylate (3) by the thermal or photochemical cheletropic reaction. Ethyl naphth[2,3-f]isoindole-1-carboxylate (3) existed in a 2H-form both in solution and as a solid, and gradually dimerized to give a dianthradiazafulvalene derivative under aerobic conditions.
ISSN:2046-2069
2046-2069
DOI:10.1039/c2ra22870j