Improved electrochemical performance of LiFePO4/C cathode via Ni and Mn co-doping for lithium-ion batteries

The pristine LiFePO4/C and Ni and Mn co-doping LiFe1−x−yNixMnyPO4/C (x = 0.01–0.04; y = 0.04–0.01) composites are synthesized for the first time by a simple high-temperature solid-state route. The structure, morphology and electrochemical performance of the samples are characterized by X-ray diffrac...

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Bibliographic Details
Published in:	Journal of power sources 2013-09, Vol.237, p.149-155
Main Authors:	Shu, Hongbo, Wang, Xianyou, Wu, Qiang, Hu, Benan, Yang, Xiukang, Wei, Qiliang, Liang, Qianqian, Bai, Yansong, Zhou, Meng, Wu, Chun, Chen, Manfang, Wang, Aiwen, Jiang, Lanlan
Format:	Article
Language:	eng
Subjects:	Applied sciences Charge Cycles Direct energy conversion and energy accumulation Discharge Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemical impedance spectroscopy Electrochemical performance Exact sciences and technology Fourier transforms High-temperature solid-state route Lithium ion batteries Lithium iron phosphate Manganese Materials Nickel Nickel and manganese co-doping Scanning electron microscopy
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Summary:	The pristine LiFePO4/C and Ni and Mn co-doping LiFe1−x−yNixMnyPO4/C (x = 0.01–0.04; y = 0.04–0.01) composites are synthesized for the first time by a simple high-temperature solid-state route. The structure, morphology and electrochemical performance of the samples are characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, scanning electron microscope (SEM), charge/discharge tests and electrochemical impedance spectroscopy (EIS). The results indicate that the Ni and Mn co-doping does not destroy the olivine structure of LiFePO4, but it can stabilize the crystal structure, lengthen the Li–O bond, decrease charge transfer resistance, enhance Li ion diffusion velocity, and thus improve its cycling and high-rate capability of the LiFePO4/C. Especially, the LiFe0.95Ni0.02Mn0.03PO4/C shows the best cycling stability and rate capability among all the doped samples. The first discharge capacity of LiFe0.95Ni0.02Mn0.03PO4/C is 145.4 mAh g−1 with the capacity retention ratio of 98.6% till 100 cycles at 1C. Even at a high rate of 10C, it still reveals a high discharge capacity of 115.2 mAh g−1. •Ni and Mn co-doping LiFePO4/C are prepared firstly by a simple solid-state route.•Ni and Mn co-doping can effectively improve the performance of LiFePO4.•LiFe0.95Ni0.02Mn0.03PO4/C shows the best rate capability and cycling stability.•Ni and Mn co-doping is an effective way to improve the performance of material.
ISSN:	0378-7753 1873-2755