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An experimental and kinetic study of alkane autoignition at high pressures and intermediate temperatures
Autoignition delay times of individual alkanes and mixtures of alkanes were measured experimentally in a high pressure, intermediate temperature, turbulent flow reactor. The mixtures are intended to simulate various natural gas compositions from around the world. Testing was conducted from 7 to 15at...
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Published in: | Proceedings of the Combustion Institute 2011, Vol.33 (1), p.301-307 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Autoignition delay times of individual alkanes and mixtures of alkanes were measured experimentally in a high pressure, intermediate temperature, turbulent flow reactor. The mixtures are intended to simulate various natural gas compositions from around the world. Testing was conducted from 7 to 15atm and from 785 to 935K which mimic the inlet conditions to the premixing zone in many modern lean premixed gas turbine engines. It is also in the kinetics region where reactions involving RO2 and H2O2 control the ignition process. The results are compared to higher temperature autoignition data from the literature which reveals several interesting differences between the two regimes. Finally, the data are compared to simulations using comprehensive chemical kinetics mechanisms to elucidate the dominant reactions at these conditions. |
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ISSN: | 1540-7489 1873-2704 |
DOI: | 10.1016/j.proci.2010.05.015 |