High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex

The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.

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Bibliographic Details
Published in:Inorganic chemistry 2014-10, Vol.53 (19), p.10009-10011
Main Authors: Palion-Gazda, Joanna, Świtlicka-Olszewska, Anna, Machura, Barbara, Grancha, Thais, Pardo, Emilio, Lloret, Francesc, Julve, Miguel
Format: Article
Language:English
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Summary:The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic501195y