Dye-sensitized solar cells based on electrospun polyacrylonitrile (PAN) nanofibre membrane gel electrolyte

•Dye sensitized solar cells based on nanofibre membrane gel electrolyte, PAN:KI:PC:I2 were fabricated and characterized.•The solar cell with membrane electrolyte of thickness 9.14μm showed the highest efficiency of 5.2%.•An identical solar cell based on corresponding liquid electrolyte showed an eff...

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Bibliographic Details
Published in:Electrochimica acta 2014-06, Vol.130, p.76-81
Main Authors: Dissanayake, M.A.K.L., Divarathne, H.K.D.W.M.N.R., Thotawatthage, C.A., Dissanayake, C.B., Senadeera, G.K.R., Bandara, B.M.R.
Format: Article
Language:English
Subjects:
Dye sensitized solar cells
Electrolytes
Electrospinning
Electrospun nanofibre based gel electrolytes
Liquids
Membranes
Nanostructure
Photovoltaic cells
Polyacrylonitriles
Solar cells
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Summary:•Dye sensitized solar cells based on nanofibre membrane gel electrolyte, PAN:KI:PC:I2 were fabricated and characterized.•The solar cell with membrane electrolyte of thickness 9.14μm showed the highest efficiency of 5.2%.•An identical solar cell based on corresponding liquid electrolyte showed an efficiency of 5.3%.•The open circuit voltage and short circuit current density of the nanofibre based solar cell were 0.67V and 13.31mAcm−2.•Dye solar cells with nanofibre gel electrolytes can yield efficiencies comparable to cells with solution electrolytes. Dye Sensitized Solar Cells (DSSCs) based on electrospun nanofibre membrane electrolytes offer several advantages over liquid electrolyte based solar cells. Nanofibre membranes having different thicknesses were prepared by electrospinning on platinum electrodes from a 11 wt% solution of polyacrylonitrile (PAN) in N,N-dimethylformamide (DMF) at an applied voltage of 8kV. The membranes were then activated by immersing in a solution containing potassium iodide (KI) (0.06g), propylene carbonate (PC) (0.8g) and iodine (I2) (0.0092g) for 30minutes to obtain “gel” type membrane electrolytes with different thicknesses. These nanofibre membrane electrolytes were used to fabricate quasi-solid state (gel) DSSCs and the performance of these solar cells were compared with DSSCs fabricated with liquid electrolyte (KI:PC:I2) and conventional PAN based gel electrolyte (PAN:KI:PC:I2). DSSC with nanofibre membrane electrolyte of thickness 9.14μm showed the highest light-to-electricity conversion efficiency of 5.2% whereas an identical cell based on corresponding liquid electrolyte showed an efficiency of 5.3%. The open circuit voltage (VOC), short circuit current density (JSc) and fill factor for the solar cell based on this electrolyte was 0.67V, 13.31mAcm−2 and 59% respectively at an incident light intensity of 1000Wm−2 with a 1.5 AM filter.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2014.02.122