Properties and decomposition of 2,6-diethylnitrosobenzene

Investigation showed that decomposition of 2,6-diethylnitrosobenzene (1) was very rapid in solution or during gas chromatography (GC) procedures. This thermal instability as well as the resulting formation of an equilibrating mixture of monometric and dimetric forms in solution complicated the analy...

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Bibliographic Details
Published in:Journal of agricultural and food chemistry 1987-07, Vol.35 (4), p.484-491
Main Authors: Wratten, Stephen J, Fujiwara, Hideji, Solsten, R. Thomas
Format: Article
Language:English
Subjects:
ANALISIS QUIMICO
ANALYSE CHIMIQUE
Biological and medical sciences
CHEMICAL ANALYSIS
Chemical and industrial products toxicology. Toxic occupational diseases
CHEMICOPHYSICAL PROPERTIES
CHLOROACETANILIDES
COMPOSICION
COMPOSITION
DEGRADATION
DETERIORO
HERBICIDAS
HERBICIDE
HERBICIDES
Medical sciences
METABOLITE
METABOLITES
METABOLITOS
PROPIEDADES FISICO-QUIMICAS
PROPRIETE PHYSICO-CHIMIQUE
Toxicology
Various organic compounds
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Summary:Investigation showed that decomposition of 2,6-diethylnitrosobenzene (1) was very rapid in solution or during gas chromatography (GC) procedures. This thermal instability as well as the resulting formation of an equilibrating mixture of monometric and dimetric forms in solution complicated the analytical data which appears to have been misinterpreted in previous metabolic studies. Reference standards were synthesized and the chromatographic and spectral properties were used to identify the thermal decomposition products of 1. N-(2,6-diethylphenyl)hydroxilamine and 3-methyl-7-ethylanthranil were the major compounds identified.
ISSN:0021-8561
1520-5118
DOI:10.1021/jf00076a011