Magneto-Structural Studies of 2-(2-Ammoniumethyl)-1-mACOthyl Pyrrolidinium Tetrachlorocuprate (II)

The (C7H18N2)CuCl4 compound crystallized in the orthorhombic system with space group P 212121 and the following unit cell are: a=7.353(3), b=11.608(5), c=16.666(8) A, and Z=4; R=0.0327, wR=0.085. The crystal structure consists of infinite zigzag one-dimensional chains of 2-(2-ammoniumethyl)-1-mACOth...

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Bibliographic Details
Published in:Journal of superconductivity and novel magnetism 2013-03, Vol.26 (3), p.693-702
Main Authors: Amamou, W, Triki, M, Dhahri, E, Zouari, F, Koumina, A, Fliyou, M
Format: Article
Language:English
Subjects:
Chemical bonds
Crystal structure
Crystallization
Distortion
Hydrogen bonding
Magnetism
Superconductivity
Unit cell
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Summary:The (C7H18N2)CuCl4 compound crystallized in the orthorhombic system with space group P 212121 and the following unit cell are: a=7.353(3), b=11.608(5), c=16.666(8) A, and Z=4; R=0.0327, wR=0.085. The crystal structure consists of infinite zigzag one-dimensional chains of 2-(2-ammoniumethyl)-1-mACOthyl pyrrolidinium dications and distorted [CuCl4]2? tetrahedral anions along the b axis. The cohesion of the atomic arrangement is ensured by hydrogen bonding (NaH?Cl).
ISSN:1557-1939
1557-1947
DOI:10.1007/s10948-012-1788-6