Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2013-08, Vol.42 (32), p.11363-11366
Main Authors: Kato, Chisato, Nishihara, Sadafumi, Tsunashima, Ryo, Tatewaki, Yoko, Okada, Shuji, Ren, Xiao-Ming, Inoue, Katsuya, Long, De-Liang, Cronin, Leroy
Format: Article
Language:English
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Summary:Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt51120k