Control of interpenetration in S-containing metal-organic frameworks for selective separation of transition metal ions

Two S-containing MOFs, interpenetrating and non-interpenetrating , were synthesized by altering solvent size. The nanoporous reveals high selective adsorption for Cu(2+) ions and has been applied as a chromatographic column for separating transition metal ions for the first time.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (11), p.1088-1090
Main Authors: Yang, Guang-Sheng, Lang, Zhong-Ling, Zang, Hong-Ying, Lan, Ya-Qian, He, Wen-Wen, Zhao, Xiao-Liang, Yan, Li-Kai, Wang, Xin-Long, Su, Zhong-Min
Format: Article
Language:English
Subjects:
Adsorption
Chromatography
Metal-organic frameworks
Metals - chemistry
Nanocomposites
Nanomaterials
Nanostructure
Organometallic Compounds - chemistry
Selective adsorption
Separation
Solvents
Solvents - chemistry
Sulfur - chemistry
Transition metals
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Description
Summary:Two S-containing MOFs, interpenetrating and non-interpenetrating , were synthesized by altering solvent size. The nanoporous reveals high selective adsorption for Cu(2+) ions and has been applied as a chromatographic column for separating transition metal ions for the first time.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc36894c