Single-Crystal-to-Single-Crystal Transformation from 1 D Staggered-Sculls Chains to 3 D NbO-Type Metal-Organic Framework through [2+2] Photodimerization

A new approach to synthesize 3D structures through a [2+2] photodimerization process has been carried out by transforming two isostructures of 1D staggered‐sculls chains [M(1,2‐chdc)(bpe)2(H2O)2]⋅H2O (M=Zn, Mn) into 3D NbO‐type metal–organic frameworks through UV irradiation in single‐crystal‐to‐sin...

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Bibliographic Details
Published in:Chemistry : a European journal 2012-06, Vol.18 (24), p.7357-7361
Main Authors: Ou, Yong-Cong, Zhi, Da-Shuai, Liu, Wen-Ting, Ni, Zhao-Ping, Tong, Ming-Liang
Format: Article
Language:English
Subjects:
crystalline-state
metal-organic frameworks
photodimerization
photoluminescence
solid-state reactions
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Summary:A new approach to synthesize 3D structures through a [2+2] photodimerization process has been carried out by transforming two isostructures of 1D staggered‐sculls chains [M(1,2‐chdc)(bpe)2(H2O)2]⋅H2O (M=Zn, Mn) into 3D NbO‐type metal–organic frameworks through UV irradiation in single‐crystal‐to‐single‐crystal mode. (see figure; bpe=trans‐1,2‐(bis(4‐pyridyl)ethene, chdc=cyclohexanedicarboxylate).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201200226