Silver(I)-catalyzed carboxylation of arylboronic esters with CO2

A variety of arylboronic esters were efficiently carboxylated with CO(2) using a simple AgOAc/PPh(3) catalyst, affording the corresponding carboxylic acids in good yield. This simple and efficient silver(i) catalytic system showed wide functional group compatibility.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (50), p.6292-6294
Main Authors: Zhang, Xiao, Zhang, Wen-Zhen, Shi, Ling-Long, Guo, Chun-Xiao, Zhang, Ling-Ling, Lu, Xiao-Bing
Format: Article
Language:English
Subjects:
Acetates - chemistry
Boronic Acids - chemistry
Carbon Dioxide - chemistry
Carboxylic Acids - chemical synthesis
Carboxylic Acids - chemistry
Catalysis
Esters - chemistry
Organophosphorus Compounds - chemistry
Silver Compounds - chemistry
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Summary:A variety of arylboronic esters were efficiently carboxylated with CO(2) using a simple AgOAc/PPh(3) catalyst, affording the corresponding carboxylic acids in good yield. This simple and efficient silver(i) catalytic system showed wide functional group compatibility.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc32045b