Effect of water on formic acid photocatalytic decomposition on TiO2 and Pt/TiO2

Physisorbed water increased the PCD rate of formic acid on TiO2 and Pt/TiO2 , but with a much larger rate increase on Pt/TiO2 . Infrared spectroscopy and temperature-programmed desorption on TiO2 P25 showed water changed the adsorbed structure of bidentate bridging formate and displaced formic acid...

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Bibliographic Details
Published in:Journal of catalysis 2010-10, Vol.275 (2), p.294-299
Main Authors: MILLER, Kristi L, CHUL WOO LEE, FALCONER, John L, MEDLIN, J. Will
Format: Article
Language:English
Subjects:
Acids
Adsorption
Catalysis
Chemical reactions
Chemistry
Exact sciences and technology
General and physical chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Spectrum analysis
Surface physical chemistry
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Water
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Summary:Physisorbed water increased the PCD rate of formic acid on TiO2 and Pt/TiO2 , but with a much larger rate increase on Pt/TiO2 . Infrared spectroscopy and temperature-programmed desorption on TiO2 P25 showed water changed the adsorbed structure of bidentate bridging formate and displaced formic acid from the surface. The effect of water on the adsorption and photocatalytic decomposition (PCD) of formic acid on TiO2 and Pt/TiO2 was investigated using transient reaction studies, temperature-programmed desorption (TPD), and Fourier transform infrared (FTIR) spectroscopy. Reaction studies indicated that physisorbed water increased the PCD rate of formic acid to a small extent on TiO 2 and to a major extent on Pt/TiO2 , but the presence of only chemisorbed water did not. FTIR spectroscopy and TPD studies indicate that the main effect of the addition of water to TiO2 that had adsorbed formic acid was the displacement of formic acid. However, FTIR spectroscopy indicated that the addition of water caused a change in the adsorbed structure of formate that may be associated with the higher reactivity. These transformations can have an important influence on elementary steps in the photocatalytic decomposition of formic acid on TiO 2 and Pt/TiO2 . [PUBLICATION ABSTRACT]
ISSN:0021-9517
1090-2694
DOI:10.1016/j.jcat.2010.08.011