Collision-Induced Transformation of the Complex Vibrational Susceptibility of a Linear Molecule Using the Example of the ν3 Band of Carbon Dioxide

The simultaneous transformation of both components of the complex isotropic vibrational susceptibility, which occurs with an increase in the density of a gas consisting of linear molecules, is traced for the first time in terms of the quantum model of strong collisions. The vibrational susceptibilit...

Full description

Saved in:
Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2024-05, Vol.98 (5), p.864-869
Main Authors: Kouzov, A. P., Filippov, N. N., Egorova, N. I., Asfin, R. E.
Format: Article
Language:English
Subjects:
Absorption spectra
Blurring
Carbon dioxide
Chemistry
Chemistry and Materials Science
Density
Line spectra
Physical Chemistry
Rotational spectra
XX SYMPOSIUM ON HIGH-RESOLUTION MOLECULAR SPECTROSCOPY (HighRus-2023)
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The simultaneous transformation of both components of the complex isotropic vibrational susceptibility, which occurs with an increase in the density of a gas consisting of linear molecules, is traced for the first time in terms of the quantum model of strong collisions. The vibrational susceptibility of the CO 2 molecule in the region of the fundamental ν 3 band is discussed in detail as a case in point. It is found that within the region of anomalous dispersion adjacent to frequency ν 3 , there is a spectral interval that is characterized by positive dispersion and exists in a fairly wide pressure range. This interval narrows upon an increase in pressure and disappears at a density of around 100 Amagat, completely blurring the branch structure of the absorption band. It is shown that allowing for the spectral exchange between the lines of the rotational structure of the band is equally important for quantitatively interpreting the spectrum of the real part of susceptibility and reproducing a correct picture of the transformation of the absorption spectrum.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024424050157